The 29-year-old actress and her partner Adam Shulman, 31, wed in Big Sur, California, on Saturday night.
The pair invited more than 100 guests to the sunset ceremony, with a rehearsal taking place on Friday evening. That dinner was held at the Ventana Inn and Spa, with the nuptials taking place on a private estate.
Anne wore a custom-made, off-the-shoulders Valentino gown, which was created in white lace. She had a matching head band and a huge veil which tumbled to the floor.
Adam opted for a simple black dinner jacket and bow tie, with the pair seen laughing and smiling together.
According to People, the venue was decorated with branches to give a nature vibe. It's thought Anne enlisted Natalie Portman's wedding planner to help organise her big day in the same place Portman married Benjamin Millepied.
The Dark Knight Rises actress had been dating Shulman for four years and got engaged last November.
"I am very much in love with him, [only] Adam totally ruined my plan," Anne said last year. "I was really actually looking forward to a little alone time, and then I fell in love like a fool!"
She said she wanted to hold off having her wedding until 2013, as "this year, its too big with two films coming out".
She said she was filming Les Miserables when the couple decided to tie the knot.
Hathaway also starred in The Devil Wears Prada and The Princess Diaries.